Hierarchically Macroporous Graphitic Nanowebs Exhibiting Ultra-fast and Stable Charge Storage Performance

The macro/microstructures of carbon-based electrode materials for supercapacitor applications play a key role in their electrochemical performance. In this study, hierarchically macroporous graphitic nanowebs (HM-GNWs) were prepared from bacterial cellulose by high-temperature heating at 2400 °C. The HM-GNWs were composed of well-developed graphitic nanobuilding blocks with a high aspect ratio, which was entangled as a nanoweb structure. The morphological and microstructural characteristics of the HM-GNWs resulted in remarkable charge storage performance. In particular, the HM-GNWs exhibited very fast charge storage behaviors at scan rates ranging from 5 to 100 V s-1, in which area capacitances ranging from ~ 8.9 to 3.8 mF cm-2 were achieved. In addition, ~ 97% capacitance retention was observed after long-term cycling for more than 1,000,000 cycles.